a) Gọi số mol Fe, Mg là a, b (mol)

=> 56a + 24b = 1,04 (1)

\(n_{H_2}=\dfrac{0,672}{22,4}=0,03\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

             a--->2a-------------->a

            Mg + 2HCl --> MgCl₂ + H₂

              b---->2b------------->b

=> a + b = 0,03 (2)

(1)(2) => a = 0,01 (mol); b = 0,02 (mol)

m_Fe = 0,01.56 = 0,56 (g)

m_Mg = 0,02.24 = 0,48 (g)

b) n_{HCl(lý thuyết)} = 2a + 2b = 0,06 (mol)

=> \(n_{HCl\left(tt\right)}=\dfrac{0,06.110}{100}=0,066\left(mol\right)\)

=> \(V_{dd.HCl\left(tt\right)}=\dfrac{0,066}{0,1}=0,66\left(l\right)\)

Mg + 2 H2SO4 (đ) -to-> MgSO4 + SO2 + 2 H2O

x_________2x__________________x(mol)

2 Fe + 6 H2SO4(đ) -to-> Fe2(SO4)3 + 3 SO2 + 6 H2O

y______3y_____________________1,5y(mol)

Ta có hpt:

\(\left\{{}\begin{matrix}24x+56y=18,4\\x+1,5y=0,6\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,3\\y=0,2\end{matrix}\right.\)

=> mMg= 0,3.24=7,2(g)

=> %mMg= (7,2/18,4).100=39,13%

=>%mFe= 60,87%

b) nH2SO4(tổng)=2x+3y=2.0,3+3.0,2=1,2(mol)

VddH2SO4=1,2/2=0,6(l)

a) Đặt \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Mg}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow56a+24b=18,4\)  (1)

Ta có: \(n_{SO_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

Bảo toàn electron: \(3a+2b=0,6\cdot2\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,2\cdot56}{18,4}\cdot100\%\approx60,87\%\\\%m_{Mg}=39,13\%\end{matrix}\right.\)

b) Ta có: \(\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Fe}=0,1\left(mol\right)\\n_{MgSO_4}=n_{Mg}=0,3\left(mol\right)\end{matrix}\right.\)

Bảo toàn nguyên tố: \(n_{H_2SO_4}=n_{SO_2}+3n_{Fe_2\left(SO_4\right)_3}+n_{MgSO_4}=1,2\left(mol\right)\)

\(\Rightarrow V_{H_2SO_4}=\dfrac{1,2}{2}=0,6\left(l\right)=600\left(ml\right)\)

a) Gọi mol Fe là a
           mol Mg là b
Ta có: 56a+24b = 18,4 (1)
Bte: 3a+2b = nS0₂.2
\(\Leftrightarrow\)3a+2b = 0,6.2  (2)
Từ(1),(2)\(\Rightarrow\left\{{}\begin{matrix}a=0,2\\b=0,3\end{matrix}\right.\)
\(\Rightarrow\)mFe = 11,2 (g) \(\Rightarrow\)%mFe = 60,87%
    mMg = 7,2 (g)  \(\Rightarrow\) %mMg = 39,13%
b)Ta có: nH₂S0₄ = 2nSo₂+nO_2(oxit)+nC0_{2(nếu có)}
\(\Rightarrow\)nH₂SO₄ = 2.0,6 = 1,2 (mol)
Có: C_M = \(\dfrac{n}{V}\)
\(\Rightarrow\)V = n.C_M = 1,2.2 = 2,4 (\(l\))

 

a, Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Al}=b\left(mol\right)\end{matrix}\right.\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH:

Fe + 2HCl ---> FeCl₂ + H₂

a--->2a------------------>a

2Al + 6HCl ---> 2AlCl₃ + 3H₂

b---->3b-------------------->1,5b

=> \(\left\{{}\begin{matrix}56a+27b=16,6\\a+1,5b=0,5\end{matrix}\right.\Leftrightarrow a=b=0,2\left(mol\right)\)

=> \(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=0,2.27=5,4\left(g\right)\end{matrix}\right.\)

b) \(C\%_{HCl}=\dfrac{\left(0,2.2+0,2.3\right).36,5}{300}.100\%=12,167\%\)

\(n_{H_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\) 
gọi nFe : a , nAl: b (a,b>0)  => 56a + 27b = 16,6 (g) 
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\) 
           a                                     a
         \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\) 
           b                                     \(\dfrac{3b}{2}\)
          
=> \(a+\dfrac{3b}{2}=0,5\) 
ta có hệ pt 
\(\left\{{}\begin{matrix}56a+27b=16,6\\a+\dfrac{3b}{2}=0,5\end{matrix}\right.\) 
=> a= 0,2 , b = 0,2 
\(\left\{{}\begin{matrix}m_{Fe}=0,2.56=11,2\left(g\right)\\m_{Al}=16,6-11,2=5,4\left(g\right)\end{matrix}\right.\) 
\(pthh:Fe+2HCl\rightarrow FeCl_2+H_2\) 
           0,2     0,4 
        \(2Al+6HCl\rightarrow2AlCl_3+3H_2\) 
           0,2    0,6 
=> \(m_{HCl}=\left(0,4+0,6\right).36,5=36,5\left(g\right)\) 
=> \(C\%=\dfrac{36,5}{200}.100\%=18,25\%\)

nN2 = 0,03

m muối - mkim loại = mNO3

=> mNO3 = 54,9-7,5 = 47,4(g)

=> n_{N(trong muối)} = nNO3 = \(\frac{47,4}{62}=0,764mol\)

BT nguyên tố N => nHNO3 = n_{N(trong muối)} +n_N2 = 0,764 + 0,03.2 = 0,824 mol

=> V = 0,824 (l)